Effect of magnesium sulfate solution on frost resistance of concrete under stress condition
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摘要: 制备了掺加20%粉煤灰的高强混凝土(HSC)、复合掺加40%粉煤灰、10%矿渣和5%硅灰的大掺量矿物掺合料混凝土(HVMAC) 和综合运用引气剂、高效减水剂、大掺量矿物掺合料、混杂纤维和膨胀剂技术的高耐久性混凝土(HDC), 采用快冻法测定了混凝土在水和5%MgSO4 (质量分数) 溶液中的抗冻性。在冻融过程中对试件采用三分点加载方式, 设定弯拉应力为破坏应力的35%。分析结果表明: 与水中冻融条件相比, MgSO4溶液分别使HSC和HDC在应力作用下的抗冻性提高了46倍和70%以上, 其抗冻融循环次数分别达到了425次以上和900次以上, 但却使HVMAC在应力作用下的抗冻性降低了67%, 抗冻融循环次数仅为75次。Abstract: The frost resistances of three kinds of concretes under flexural stress subjected to water and 5% MgSO4 (mass fraction) solution were studied by using accelerated freezing-thawing method. The considered concretes include high strength concrete (HSC) added with 20% fly ash (20% of binder mass), high-volume mineral admixture concrete (HVMAC) added with 40% fly ash, 10% slag and 5% silica fume, and high durable concrete (HDC) added with high-volume mineral admixture, air-entraining agent, superplasticizer, fibres and expansion agent. Third point loading method was applied on the specimens in the process of freezing-thawing cycle, and the enacted flexural stress was 35% of failure stress. Analysis result shows that the frost resistances of HSC and HDC respectively increase 46 times and more than 70% under flexural stress subjected to MgSO4 solution as compared with water, and their anti-freezing-thawing cycles are respectively more than 425 times and 900 times. But the frost resistance of HVMAC decreases by 67% under flexural stress, and its anti-freezing-thawing cycles are only 75 times.
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表 1 原材料化学成分
Table 1. Chemical compositions of raw materials %
表 2 纤维的性能指标
Table 2. Performance indices of fibres
表 3 混凝土的配合比和性能
Table 3. Mixed proportions and properties of different concretes
混凝土 材料用量/ (kg·m-3) 减水剂/% 坍落度/mm 28 d抗压强度/MPa 水泥 粉煤灰 矿渣 硅灰 膨胀剂 砂 石子 水 HSC 304 76 0 0 0 775 1 235 171 0.80* 65 59.5 HVMAC 270 240 60 30 0 669 1 104 139 0.85** 80 50.7 HDC 210 240 60 30 60 669 1 104 142 1.20** 100 60.6 注: “*”代表JM-B型萘系高效减水剂; “**”代表HP400R型聚羧酸缓凝高效减水剂。 -
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