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船舶碳捕集、利用与封存技术综述

卢明剑 董胜节 严新平 李珂 李晓东 周晓

卢明剑, 董胜节, 严新平, 李珂, 李晓东, 周晓. 船舶碳捕集、利用与封存技术综述[J]. 交通运输工程学报, 2024, 24(2): 1-19. doi: 10.19818/j.cnki.1671-1637.2024.02.001
引用本文: 卢明剑, 董胜节, 严新平, 李珂, 李晓东, 周晓. 船舶碳捕集、利用与封存技术综述[J]. 交通运输工程学报, 2024, 24(2): 1-19. doi: 10.19818/j.cnki.1671-1637.2024.02.001
LU Ming-jian, DONG Sheng-jie, YAN Xin-ping, LI Ke, LI Xiao-dong, ZHOU Xiao. Review on ship-based carbon capture, utilization and sequestration technology[J]. Journal of Traffic and Transportation Engineering, 2024, 24(2): 1-19. doi: 10.19818/j.cnki.1671-1637.2024.02.001
Citation: LU Ming-jian, DONG Sheng-jie, YAN Xin-ping, LI Ke, LI Xiao-dong, ZHOU Xiao. Review on ship-based carbon capture, utilization and sequestration technology[J]. Journal of Traffic and Transportation Engineering, 2024, 24(2): 1-19. doi: 10.19818/j.cnki.1671-1637.2024.02.001

船舶碳捕集、利用与封存技术综述

doi: 10.19818/j.cnki.1671-1637.2024.02.001
基金项目: 

中国工程院战略研究与咨询项目 2022-HYZD-07-02

国家自然科学基金项目 51920105014

详细信息
    作者简介:

    卢明剑(1987-),男,江苏宿迁人,武汉理工大学副研究员,工学博士,从事船舶新能源与节能减排研究

    通讯作者:

    严新平(1959-),男,江西莲花人,中国工程院院士,武汉理工大学教授,工学博士

  • 中图分类号: U664

Review on ship-based carbon capture, utilization and sequestration technology

Funds: 

Strategic Research and Consulting Project of Chinese Academy of Engineering 2022-HYZD-07-02

National Natural Science Foundation of China 51920105014

More Information
  • 摘要: 追踪了国内外围绕船舶碳捕集、利用与封存(CCUS)技术开展的研究,梳理了重点内容和主要研究成果;从CCUS不同技术路径的优缺点出发,分析了目前CCUS技术在船舶上的应用可行性;针对发展迅猛的液化天然气船舶,提出了开展CCUS的技术路线;总结了目前船舶CCUS技术存在的问题,针对性地提出了建议,并探讨了船舶CCUS关键技术的发展方向。研究结果表明:船舶CCUS技术可以在短期内显著减排,且适用于营运和新造在内的绝大多数含碳燃料船舶;国外正在积极部署船舶CCUS技术实船验证研究,但国内的研究多处于概念设计与仿真研究阶段;由于改造简单,技术成熟度高且成本低,燃烧后捕集法中的化学吸收法目前最适用于船舶碳捕集,但要解决能耗高和系统尺寸大等问题,需加快探索性能更优良的先进化学溶剂及更具革命性的捕集方法;液态存储是目前最成熟的存储方式,但还需要提升其安全性与经济性;亟需加快构建以大型CO2运输船为主的储运方式,推进港口与海洋平台CO2转驳、接收的基础设施建设;CO2在海洋油气田驱油驱气、淡化海水及能源催化重整等领域应用前景广阔,但船舶CO2利用技术亟待规模化、产业化和相关产业技术协同发展;将液态CO2或干冰进行海洋封存是未来的发展趋势,但亟需完善相关标准和法律法规,推动封存配套装备和技术开发;需要探索出一整套标准化、系统化的碳排放管理模式,推动CCUS技术配套发展,构建完整、绿色、经济、高效的船舶CCUS产业链。

     

  • 图  1  船舶碳捕集技术路线

    Figure  1.  Ship-based carbon capture technology route

    图  2  海德威船用CCUS系统

    Figure  2.  Headway marine CCUS system

    图  3  碳捕集路径

    Figure  3.  Carbon capture pathways

    图  4  碳捕集技术成熟度国内外对比

    Figure  4.  Comparison of maturities of domestic and foreign carbon capture technologies

    图  5  液态CO2技术路线的实用性优势

    Figure  5.  Practical advantages of liquid CO2 technology route

    图  6  CO2利用技术路线

    Figure  6.  CO2 utilization technology route

    图  7  海水淡化

    Figure  7.  Seawater desalination

    图  8  HyMethShip概念

    Figure  8.  Concept of HyMethShip

    图  9  苯乙烯氧化/CO2环加成

    Figure  9.  Styrene oxidation/CO2 cycloaddition

    图  10  穿甲弹状干冰制造模具

    Figure  10.  Armor-piercing bullet shaped dry ice manufacturing mold

    图  11  远洋船舶CCUS技术应用路线

    Figure  11.  Application pathway of CCUS technology in ocean-going ships

    表  1  国外主要船舶CCUS项目

    Table  1.   Major foreign ship-based CCUS projects

    年份 2010 2019 2020 2021 2021 2022
    项目名称 Eurostar Decarbon ICE Carbon Capture on the Ocean 乙烯船“Clipper Eos”号CCS系统改造安装 Filtree气体清洁系统 大宇造船LNG船舶碳捕集
    技术路线 化学吸收→液化存储→转运码头 低温处理→制流线型干冰→海洋封存 利用燃烧后捕集法,聚焦于捕集装置开发 化学吸收 模块捕集→CO2电池存储→岸上利用 化学吸收→CO2矿化→吸收溶剂再生循环利用
    减排效果(目标) CO2减排65% 减排90%以上 验证海上碳捕集系统紧凑性及稳定运行规格要求 深海船队零碳航行
    下载: 导出CSV

    表  2  三种碳捕集技术对比

    Table  2.   Comparison of three carbon capture technologies

    捕集方法及评价指标 燃烧前捕集 富氧燃烧 燃烧后捕集法
    改造量及投入成本 开发氢燃料发动机,增添反应罐等,投入成本大 改造发动机结构、系统及材料,投入成本大 仅改造发动机尾气处理系统,投入成本低
    安全及稳定性 系统复杂,可靠性低 涉及燃烧过程改造,存在高温危险性操作 对尾气进行处理,操作风险小
    下载: 导出CSV

    表  3  燃烧后碳捕集方法对比

    Table  3.   Comparison of post-combustion carbon capture methods

    捕集方法及评价指标 化学吸收法 物理吸附法 膜分离法 低温分离法
    技术制约 适合船舶尾气中低浓度CO2分离 选择性不高,分离效果差 不耐杂质,分离效果差 适用于高浓度CO2分离
    紧凑性 安装尺寸较大的吸收塔、再生塔及各种换热器等装置 变温吸附占地大,变压吸附受吸附床及压缩装置限制 占地小,紧凑性最好 压缩、制冷装置占地大
    每吨CO2捕集能耗/GJ 4.00~6.00 2.89~3.59 1.96~2.85 3.11
    每吨CO2捕集成本/美元 64.1~64.8 40.0~63.0 23.0 32.7
    下载: 导出CSV

    表  4  船舶CO2利用或封存技术优缺点

    Table  4.   Advantages and disadvantages of ship-based CO2 utilization or sequestration technology

    CO2存储、封存状态 利用或封存 接收或封存方式 优点 缺点
    液态存储 回收利用 专用CO2运输船、自身船舶运输到港口 液态制冷能耗低,所占船舶空间较小;CO2可以售卖给利用厂家,产生经济效益;资源循环利用,如制成CH3OH还可以回用于船舶燃料;泄露风险较小,对人和生态环境影响较小 国际航行船舶产生CO2量较大,需要占用载货体积;船上存储有安全隐患,需要专业的接收处置方式;IMO尚未有这方面的规则出台;港口或运输船接收资质要求、管理要求、收费机制等尚未明确;不一定所有港口都有接收处理能力
    液态封存 海洋封存 利用管道注入海洋 封存时间长,不占用船舶载货空间,不用建设专用的CO2运输船,不用港口建设专用接收设备及运输系统,对海洋环境及生物影响小 管道注入需要航行做停留,以避免管道断裂造成泄露;注入区域限制较多(温度和压力);管道注入方案从未在航行船舶上做过论证研究
    固态封存 固态抛投进入海洋 制成干冰需大量能耗;相关干冰制取方法不成熟,如气化制干冰CO2损失较多;IMO尚未出台关于允许干冰抛投区域、原则、评估等政策;抛投封存技术方案尚未成熟;不产生任何经济效益
    下载: 导出CSV
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  • 收稿日期:  2023-11-20
  • 网络出版日期:  2024-05-16
  • 刊出日期:  2024-04-30

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