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TAN Yi-qiu, LI Guan-nan, DAN Li-yan, LYU Hui-jie, MENG An-xin. Research progress of bitumen microstructures and components[J]. Journal of Traffic and Transportation Engineering, 2020, 20(6): 1-17. doi: 10.19818/j.cnki.1671-1637.2020.06.001
Citation: TAN Yi-qiu, LI Guan-nan, DAN Li-yan, LYU Hui-jie, MENG An-xin. Research progress of bitumen microstructures and components[J]. Journal of Traffic and Transportation Engineering, 2020, 20(6): 1-17. doi: 10.19818/j.cnki.1671-1637.2020.06.001
shu

Research progress of bitumen microstructures and components

doi: 10.19818/j.cnki.1671-1637.2020.06.001
  • 1.

    School of Transportation Science and Engineering, Harbin Institute of Technology, Harbin 150090, Heilongjiang, China

  • 2.

    State Key Laboratory of Urban Water Resource and Environment, Harbin Institute of Technology, Harbin 150090, Heilongjiang, China

Funds:

National Natural Science Foundation of China U1633201

More Information
  • Author Bio:

    TAN Yi-qiu(1968-), female, professor, PhD, yiqiutan@163.com

  • Received Date: 2020-07-12
  • Publish Date: 2020-06-25
    Abstract
  • To further promote the development of bitumen microstructures and components, the research progresses of bitumen chemical component, microstructure theory, simulation, and experimental methods were summarized. The physical and chemical properties of four components of bitumen, and the influence of wax and heteroatoms on bitumen microstructure were investigated. The bitumen microstructure was studied by combining bitument colloid theory and modified Yen model. The molecular dynamics and phase-field method commonly used in bitumen microstructure research were analyzed. The research progress of gel permeation chromatography, infrared spectroscopy, small angel scattering technology, microscopy technique in the study of bitumen microstructure was summarized. Research results show that bitumen should be regarded as a chemical continuum system. The molar mass, hydrogen to carbon ratio, and the polarity of molecules in bitumen gradually change in the order of saturate, aromatic, resin, and asphaltene. Waxes with a main carbon chain greater than C40 can be regarded as asphaltene components. The oxygen, nitrogen, and sulfur heteroatoms of bitumen exist in the form of characteristic functional groups in the polar components such as asphaltenes, resins, and aromatics, which are key parameters of bitumen molecular structure and are closely related to the adhesion properties of bitumen-aggregates. The colloidal state of bitumen is the microstructural basis of the viscoelastic behavior of asphalt. The modified Yen model can further explain the bitumen colloid theory. When asphaltene concentration is lower than the critical concentration of nano-aggregates, bitumen microstructure turns to the sol. When asphaltene concentration is gradually higher than the critical concentration of nano-aggregates, clusters and flocculation appear in bitumen, and bitumen microstructure changes from sol to gel. The molecular dynamics and phase-field method are widely used to simulate bitumen microstructure, but both two simulation methods simplify bitumen microstructure, there is still existing a huge challenge in the multi-scale simulation method based on microstructure simulation. One of the important development directions in bitumen material science is to combine bitumen chemical composition, bitumen colloid theory, and rheology characteristics to establish a complete mechanical constitutive relationship.

     

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